Russia has warned the US that launching air strikes in response to a suspected chemical attack in Syria could spark a war between the two countries.
"The immediate priority is to avert the danger of war," Moscow's UN ambassador Vassily Nebenzia said on Thursday.
He accused Washington of putting international peace at risk and said the situation was "very dangerous".
Western powers are thought to be preparing for strikes but Russia, a Syrian ally, opposes such action.
"We cannot exclude any possibilities, unfortunately," Mr Nebenzia told reporters after a private meeting of the UN Security Council in New York.
He said there was a heightened "danger of escalation" because of the Russian military presence in Syria.
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Senior Russian figures, including the head of the military, have warned that US missiles will be shot down and their launch sites targeted if Russian personnel come under threat.
Mr Nebenzia also called for the UN Security Council to meet again on Friday to discuss the possibility of Western military action.
The White House says it is continuing to assess intelligence and talk to its allies on how to respond.
Meanwhile, the Organisation for the Prohibition of Chemical Weapons (OPCW) says experts are travelling to Syria and will start investigations on Saturday.
Why is the West considering military action?The call for action comes after a suspected chemical attack on the rebel-held town of Douma in the Eastern Ghouta on Saturday, which killed dozens of people, according to opposition activists, rescue workers and medics.
Chemical weapons attacks are suspected to have taken place in Syria before. Last year, the US launched a retaliatory strike against one said to have taken place in Khan Sheikhoun.
President Bashar al-Assad's government - which receives military backing from Russia - has denied involvement in any chemical attack, calling the reports "fabricated".
After six weeks of heavy fighting and an estimated 1,700 civilian deaths in the Eastern Ghouta region, the Syrian government is now said to have control of the area, which lies just outside of Damascus.
The final evacuations of about 4,000 remaining Islamist fighters and civilians continued on Friday, according to the UK-based Syrian Observatory for Human Rights monitoring organisation.
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The Violations Documentation Center (VDC), which records alleged violations of international law in Syria, said bodies were found with foam at the mouth, discoloured skin and burns to the eyes.
On Thursday, unnamed US officials said they had blood and urine samples from victims which had tested positive for chlorine and a nerve agent, according to NBC News.
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The US ambassador to the UN, Nikki Hayley, told the network: "We definitely have enough proof, but now we just have to be thoughtful in our action."
French President Emmanuel Macron also said he had "proof" that the Syrian government had attacked Douma with chemical weapons, without giving further details.
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